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Question: 24 for a system consisting of n atoms and possessing...

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2.4. For a system consisting of N atoms and possessing n such Schottky defects write down the Helmholtz free energy F(n). For a system in thermal equilibrium in a heat bath at temperature T the Helmholtz free energy is a minimum. Use this property to determine the temperature dependence of the concentration n/N of Schottky defects.

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