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Question: 3 draw and label a compound that contains diastereotopic hydrogens...

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3) Draw and label a compound that contains diastereotopic hydrogens and one that contains enantiotopic hydrogens that are different from what we have discussed already. 14) In the structure below, determine the maximum multiplicity of each signal if the coupling constants are not equal. 15) You learned last semester that large groups like that in t-butyleyclohexane prefer to be in the equatorial position over the axial position. In fact the ratio of equatorial: axial for of t-butylcyclohexane is 99: A. Draw the two conformations. B. Given this information and what you learned in lecture concerning HNMR for cyclohexanes, how many different signals would you expect to see for this molecule C. Give the multiplicity you would expect for the proton on the carbon bearing the t-butyl group.

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